C. Botteghi, S. Paganelli, F. Moratti, M. Marchetti, R. Lazzaroni, R. Settambolo, O. Piccolo. Use of 3-Azabicyclo[3.2.2]nonane in the Mannich Reaction II. as a Selective and An Efficient Reducing Agent. Chung, H. Lau, Kenneth A. Hodd, William W. Wright. Role of neighboring groups in replacement reactions. Modified Borohydride Agents, 1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane Tetrahydroborate (BAAOTB) versus Tetrabutylammonium Tetrahydroborate (TBATB). Guanylthiourea derivatives as potential antimalarial agents: Synthesis, in vivo and molecular modelling studies. Because hydride can be thought of as a proton plus two electrons, we can think of conversion of a ketone or an aldehyde to an alcohol as a two-electron reduction. Herbert C. Brown and P. Veeraraghavan Ramachandran. Belmont, J.L. Redox Properties of Plant Biomass-Derived Black Carbon (Biochar). The most common reagents for reduce aldehydes and ketones to alcohols are sodium borohydride and lithium aluminum hydride. 271 publications. Weiliang Xu, Hongjun Fan, Guotao Wu, Ping Chen. Synthesen biskationischer, trypanocider 1-Benzofuran-Verbindungen. D-Homo-dehydro-epi-androsteron und eine neue Synthese des D-Homo-testosterons. Journal of Industrial and Engineering Chemistry. Find more information about Crossref citation counts. Aerobic Fate of the C-3‘-Thymidinyl Radical in Single-Stranded DNA. Kinetics of the thermal decomposition of tetramethylammonium aluminum hydride. 3-Epi-digitoxigenin. d,l Photocycloaddition of thiocarbonyl compounds to olefins. Pratibha Kumari, Renu Gautam, Harshit Yadav, Vikas Kushwaha, Avinash Mishra, Shilpi Gupta, Veena Arora. Synthesis of 2-chromanol by hydroformylation of 2-hydroxystyrene derivatives. William J. Spillane, G. Anthony Benson. Accelerated Aging of Cellulosic Textiles at Different Temperatures. En Si Wang, Yuen Min Choy, Henry N.C. Wong. Journal of Molecular Catalysis A: Chemical. I. Zeitschrift f�r anorganische und allgemeine Chemie. Preparation of Aldehydes from Alcohols Aldehydes and ketones can be formed by the oxidation of primary and secondary alcohols respectively. 1,3,2-Oxazastibinanes: Novel six-membered heterocycles. Part II. A novel carbocatalytic hydride transfer strategy for efficient reduction of structurally different aldehydes and ketones in water. Selective nitrogen functionalization of phosphorus-containing activated carbons. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Didier Huber, Gérard Leclerc, Guy Andermann. Sei-ichiro Imamura, Masaaki Teramoto, Takao Sumi, Hideki Aomi, Hiroshi Teranishi, Yoshinobu Takegami. ) Verónica López Durán, Per A. Larsson, Lars Wågberg. M A Armitage, M M Cashyap, D Saunders. Mitteilung. Guillaume Braesch, Antoine Bonnefont, Vincent Martin, Elena R. Savinova, Marian Chatenet. New Syntheses of Borohydrides. -Aldosteron. Georges A. Lahoud,, Anne L. Hitt, and. Part I ? K. Nagarajan, Ch. Studies on the Cooking Mechanism of Wood. Urban. N Cory Williams, Mario Luis, Ivan Lopez, Adiel Coca. Yuho Tsuno, Masami Sawada, Takahiro Fujii, Yasuhide Yukawa. Susumu Sakata, John M. Hayes, Michel Rohmer, Alan B. Hooper, Myriam Seemann. Calcium chloride substitution in sodium borohydride. Home » ORGANIC CHEMISTRY » Alcohols » Alcohol synthesis by reduction of aldehydes and ketones. Coupling osmium complexes to epoxy-functionalised polymers to provide mediated enzyme electrodes for glucose oxidation. Contributions of disinfection by-products to activity inducing chromosomal aberrations of drinking water. Zugleich eine Studie über die Reduktionswirkung von Lithiumaluminiumhydrid, Lithiumborhydrid und Natriumborhydrid in verschiedenen Lösungsmitteln. Ramanujam K. Raman, Nurul A. Choudhury, Ashok K. Shukla. Unexpected Selectivity in Sodium Borohydride Reductions of α-Substituted Esters: Experimental and Theoretical Studies. Mitteilung. Subba Rao, M.K. D. A. Lyttle, E. H. Jensen, and W. A. Nickel 3D Structures Enhanced by Electrodeposition of Nickel Nanoparticles as High Performance Anodes for Direct Borohydride Fuel Cells. Organic Chemistry Quizzes, Practice Exams, Study Guides, Reaction Guides and More! HPLC determination of vitamin B6 in foods after pre-column derivatization of free and phosphorylated vitamers into pyridoxol. 5-Methoxyl participation in some solvolysis reactions. Domhnall MacAodha, Maria Luisa Ferrer, Peter Ó Conghaile, Paul Kavanagh, Dónal Leech. A STABLE, SELECTIVE AND VERSATILE REDUCING AGENT. A. Plattner. Reduction of Carbonyl Compounds with Complex Hydrides. V. Leclerc, P. Depreux, D. Lesieur, D.H. Caignard, P. Renard, P. Delagrange, B. Guardiola-Lemaitre, P. Morgan. Biochimica et Biophysica Acta (BBA) - General Subjects. X. Solvolysis of 3- and 4-Substituted 1-(1-Naphthylethyl) Chlorides. Synthesis, NMR Characterization, and a Simple Application of Lithium Borotritide. In the ). Taking the Stress Out of Learning Science. In metal hydrides reductions the resulting alkoxide salts are insoluble and need to be hydrolyzed (with care) before the alcohol product can be isolated. Aldehydes produce 1º-alcohols and ketones produce 2º-alcohols. Improved Flavodoxin Inhibitors with Potential Therapeutic Effects against Helicobacter pylori Infection. An aldehyde plus two electrons and two protons becomes an alcohol. Synthetic studies on prehispanolone and 14,15-dihydroprehispanolone. Unni, K. Venkataraman. Simple Volumetric Assay for Sodium Borohydride. The action of diborane and of sodium borohydride-boron trifluoride-etherate on anthraquinones: a new synthesis of aloe-emodin and citreorosein and a general method for the reduction of anthraquinones to anthracene derivatives. Desaminierungsreaktionen, 28. Similar to ketones, aldehydes biocatalytic reduction is one of the most important and pratical reaction for alcohols (Andrade et al., 2006) which can be transformed to synthetise industrially important chemicals.
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